A b i n i t i o configuration-interaction study of the photoelectron spectra of small sodium cluster anions
- 15 September 1989
- journal article
- letter
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 91 (6) , 3794-3795
- https://doi.org/10.1063/1.456862
Abstract
We find that the ab initio direct configuration‐interaction calculations on Na−2–5 and Na2–5 account for the observed patterns of photoelectron spectra, reproduce the observed excitation energies in a semiquantitative way and permit an assignment of cluster geometries.Keywords
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