Vibrational spectra of halides and complex halides. Part V. Tungsten chloride pentafluoride
- 1 January 1968
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 1131-1133
- https://doi.org/10.1039/j19680001131
Abstract
Infrared and laser-Raman spectra of WF5Cl are reported and assigned on the basis of C4v symmetry. A tungsten–chlorine bond distance of 2·10 Å is estimated from the P–R separation of ν1. This, and the high value of ν1, suggests the presence of some π-contribution to the W–Cl bond.Keywords
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