Cathodic Action of the Uranyl-Malate Complexes at the Dropping Mercury Electrode
- 1 January 1964
- journal article
- Published by The Electrochemical Society in Journal of the Electrochemical Society
- Vol. 111 (11) , 1283-1286
- https://doi.org/10.1149/1.2425980
Abstract
The uranyl ion in malic acid solution has been investigated by polarography and conductometry. Evidence has been presented for the existence of three kinds of chelate species, , , and . Their structures and electrode reactions at various pH values have been established. In the temperature range from 9.1° to 21.5°C the chelates exist as a dimer. On raising the temperature to 28.5°C the depolymerization takes place completely to form a monomer.Keywords
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