Reaction of 1,2,3-thiadiazoles with base. II. Thioneesters from thioketene intermediates
- 1 July 1968
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 46 (13) , 2251-2254
- https://doi.org/10.1139/v68-366
Abstract
Alkynethiolates, generated from 1,2,3-thiadiazoles by a strong base, react with alcohols and alkanethiols to give thioneesters and dithioesters respectively. In this manner were prepared: dimethyl monothionemalonate, (methoxythiocarbonyl)acetamide, methyl phenylthioneacetate, and ethyl phenyldithioacetate. 2,ω-Diphenyl-1,4-dithiafulvene results from the reaction between lithium 2-phenylethynethiolate and water.Keywords
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