Experiments on N2(A 3Σu+). III. Excitation of Hg

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15 March 1968

journal article
research article
Published by AIP Publishing in The Journal of Chemical Physics

Vol. 48 (6) , 2572-2574
https://doi.org/10.1063/1.1669484

Abstract

The rate coefficients of the reaction

N_{2} {(A}^{3} Σ_{u}^{+} {) + Hg→N}_{2} {(X}^{1} {Σ) + Hg(3P}_{1}^{0})

have been measured for

υ′ = 0

and 1 as

{k(0) = 8 × 10}^{−12} {cm}^{3} / \sec

and

{k(1) = 9 × 10}^{−12} {cm}^{3} / \sec

. The total rate coefficient for de‐excitation of

N_{2} {(A}^{3} Σ_{u}^{+})

by Hg is 1.4 × 10⁻¹¹ cm³/sec.

This publication has 4 references indexed in Scilit:

Experiments on N2(A 3Σu+). I. Reaction with N
The Journal of Chemical Physics, 1968
Lifetime and diffusion coefficient of the A 3Σu+ state of N2
Planetary and Space Science, 1967
Spectroscopic observations on the active modification of nitrogen. —V
Proceedings of the Royal Society of London. Series A, Containing Papers of a Mathematical and Physical Character, 1917
Spectroscopic investigations in connection with the active modification of nitrogen. II―Spectra of elements and compounds excited by the nitrogen
Proceedings of the Royal Society of London. Series A, Containing Papers of a Mathematical and Physical Character, 1912