Association and dissociation in the electrochemical diffuse layer
- 1 January 1966
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Transactions of the Faraday Society
- Vol. 62, 1907-1914
- https://doi.org/10.1039/tf9666201907
Abstract
A local thermodynamical investigation of the real dissociation constant K in the diffuse layer shows that it is theoretically possible to calculate the ratio K/K′, where K′ is the dissociation constant in the bulk phase. This ratio is a function of the field intensity. According to the values of the polarization terms and of the molar volumes of the components, the dissociation constant K in the double layer can be greater, equal or smaller than the one in the bulk.Keywords
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