Mild and General Cross-Coupling of (α-Alkoxyvinyl)silanols and -silyl Hydrides
- 7 September 2000
- journal article
- Published by American Chemical Society (ACS) in Organic Letters
- Vol. 2 (20) , 3221-3224
- https://doi.org/10.1021/ol0064112
Abstract
(α-Alkoxyvinyl)silanols and (α-alkoxyvinyl)silyl hydrides are efficiently converted to aryl vinyl ethers by a palladium(0)-catalyzed cross-coupling reaction with aryl halides in the presence of tetrabutylammonium fluoride or hydroxide. Yields are generally high, and the reaction is compatible with a wide range of functional groups.Keywords
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