Preparative-scale organometallic chemistry in supercritical fluids; isolation of [Cr(CO)5(C2H4)] as a stable solid at room temperature
- 1 January 1993
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 24,p. 1814-1815
- https://doi.org/10.1039/c39930001814
Abstract
A miniature flow reactor has been developed for photochemical reactions in supercritical fluids; [Cr(CO)5(C2H4)] is isolated, for the first time, by the UV photolysis of [Cr(CO)6] in supercritical C2H4 at room temp, with a yield of ca. 40 mg per hour at ca. 80% purity as estimated by IR spectroscopy.Keywords
This publication has 0 references indexed in Scilit: