Diazo‐, azo‐ and azidoazoles, and related compounds. 1. Synthesis of naphthoazolo‐as‐triazines from diazoazoles and 2‐naphthol

Publisher Website
Google Scholar
Abstract
Azo derivatives prepared by coupling 2‐diazoimidazole, 3(5))diazopyrazole, 3(5)diazo‐s‐triazole, 4(5)diazo‐v‐triazole and diazotetrazole with β‐naphthol have been cyclized to the corresponding naphthoazolo‐as‐triazines, an heterocyclic system related to azasteroids. The structure of the products have been elucidated. A consistent mechanism for the cyclization is proposed.