An intramolecular, four-co-ordinate, σ-allyl transition state in the syn–anti exchange in a π-allylpalladium complex
- 1 January 1971
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 16,p. 935-936
- https://doi.org/10.1039/c29710000935
Abstract
A novel instance of preferential syn–anti-isomerisation about the substituted carbon atom of an asymmetrically substituted π-allylpalladium chloride dimer is accounted for in terms of an intramolecular, four-co-ordinate σ-allyl transition state.Keywords
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