Thermodynamic study on oxime complexes: the relative co-ordinating power of ketone, oxime, and amine functional groups
- 1 January 1974
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 1,p. 47-51
- https://doi.org/10.1039/dt9740000047
Abstract
Thermodynamic data (ΔG, ΔH, ΔS) are reported for the reaction of the diamine-dioxime 4,4,9,9-tetramethyl-5,8-diazadodecane-2,11-dione dioxime with protons and copper(II) ions in aqueous solution. Data for the formation of the copper complexes are compared with data for the analogous diamine-diketone 4,4,9,9-tetramethyl-5,8-diazadodecane-2,11-dione and the analogous tetra-amine 2,11-diamino-4,4,9,9-tetramethyl-5,8-diazadodecane. The relative co-ordinating powers of different donor groups in these structurally related ligands are amine > oximato oxime > ketone (H2O).Keywords
This publication has 0 references indexed in Scilit: