The synthesis of N-heterocycles using ortho-metallated primary benzylamine complexes of palladium(II) and platinum(II)
- 1 January 1984
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 17,p. 1165-1166
- https://doi.org/10.1039/c39840001165
Abstract
The synthesis of the isoindolinimines (5) by the insertion of isocyanides into the metal–carbon bond of the ortho-palladated primary benzylamine complex (1a) is described; the novel oxidative addition and susbsequent reductive elimination of the ortho-metallated primary benzylamine–platinum complex (6) yields 3-oxo-1,2,3,4-tetrahydroisoquinoline (8).Keywords
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