Ein Ylidkomplex des Rutheniums mit drei-und viergliedrigen Metallocyclen / An Ylide Complex of Ruthenium with Three-and Four-Membered Metallocycles
Open Access
- 1 May 1980
- journal article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung B
- Vol. 35 (5) , 584-587
- https://doi.org/10.1515/znb-1980-0514
Abstract
A spirometallocyclic complex of ruthenium with (CH3)2P(CH2)2, (CH3)2PCH2 and two (CH3)3P ligands (formula 5) is synthesized from (CH3)2P(CH2)2Li and trans-[(CH3)3P]4RuCl2 in the molar ratio 2:1. Two equivalents of (CH3)3P are liberated and the ionic complex trans-[(CH3)3P]4Ru[CH2P(CH3)3]Cl +Cl- is formed as a by-product. The products were characterized by analytical and spectroscopic data.Keywords
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