DEFLUORINATIVE COUPLING REACTIONS OF gem-DIFLUOROOLEFINS WITH ORGANOLITHIUM REAGENTS. NOVEL, FACILE METHODS FOR CHAIN ELONGATIONS OF ALDEHYDES LEADING TO AMIDES, ACETYLENES, AND KETONES
- 5 August 1980
- journal article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 9 (8) , 935-938
- https://doi.org/10.1246/cl.1980.935
Abstract
Three types of coupling reactions of gem-difluoroolefins derived easily from aldehydes with lithium reagents (R′Li and R′2NLi) are described which constitute the facile procedures for conversions of aldehydes (RCHO) to amides (RCH2CONR′2), acetylenes (R–C≡C–R′), and ketones (RCH2COR′).This publication has 4 references indexed in Scilit:
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