Effect of axial azide on the selective, low temperature metalloporphyrin-catalysed reactions of isobutane with molecular oxygen
- 1 January 1989
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 16,p. 1187-1188
- https://doi.org/10.1039/c39890001187
Abstract
Azido(tetraphenylporphyrinato) complexes of CrIII, MnIII, and FeIII catalyse selective, low temperature hydroxylation of isobutane with molecular oxygen and provide many turnovers in the absence of added co-reductants.Keywords
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