Energy dependence of the reaction of CH+2 with HCl
- 15 August 1991
- journal article
- letter
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 95 (4) , 3020-3021
- https://doi.org/10.1063/1.460907
Abstract
The energy dependence of the reaction of CH+2 with HCl has been investigated using a selected ion flow drift tube (SIFDT) in the center‐of‐mass kinetic energy (KEc.m.) range from 0.04–2 eV. The reaction rate coefficient is fast at near thermal energies (k∼1.5×10−9 cm3 s−1) but decreases dramatically with increasing KEc.m. to k−10 cm3 s−1 at 2 eV, which is quite uncommon for a thermally fast ion–molecule reaction.Keywords
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