Abstract
Stilbericoside, a new iridoid isolated from Stilbe ericoides, is shown to have structure 1. The relative configuration is deduced mainly from NMR spectra and double resonance experiments. Because of the great similarity of their NMR spectra 1 and unedoside, a known iridoid, which also occurs in Stilbe ericoides, very probably have the same relative configuration. Unedoside therefore should be represented by formula 2 rather than by the hitherto accepted formula 3 .

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