EPR of Ti3+in CuAlS2

Abstract
An EPR analysis of CuAlS2:Ti3+ yields the following spin Hamiltonian parameters: g/sub ///=1.9018, gperpendicular to =1.9784, mod A/sub ///47,49 mod =26.3*10-4 cm-1, mod Aperpendicular to 47,49 mod =8.3*10-4 cm-1. Hyperfine interaction with four second-shell 27Al nuclei splits the resonance line into 21 well resolved components, the interaction parameters being mod a mod =7.32*10-4 cm-1, mod b mod =0.32*10-4 cm-1.

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