Absolute configuration of the C18 juvenile hormone: application of a new circular dichroism method using tris(dipivaloylmethanato)praseodymium
- 1 January 1971
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 20,p. 1235-1236
- https://doi.org/10.1039/c29710001235
Abstract
The absolute configuration of the C18 juvenile hormone has been established as being (10R : 11S)-(I); this is based on clarification of the mode of epoxide cleavage, and a determination of the chirality of the resultant α-glycol by a new c.d. method employing Pr(dpm)3.Keywords
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