Synthesis of Glycosyl Esters and Glycosyl Hemiacetals From Methylthioglycosides
- 1 January 1990
- journal article
- research article
- Published by Taylor & Francis in Journal of Carbohydrate Chemistry
- Vol. 9 (2-3) , 333-343
- https://doi.org/10.1080/07328309008543836
Abstract
Glycosyl esters constitute a widespread family of natural products such as anti-tumor agents,1 antibiotics,2 terpenoid glycosides,3 plant pigments4 and other substances.5 It has been shown that aromatic carboxylic acids are metabolized by humans as glycosyl esters,6 and D-glucopyranosyl fatty acid esters were found to inhibit the growth of leukemia cells7 and plant growth.8 The synthesis of a prodrug in the g form of a glycosyl ester has been reported.9 In synthetic chemistry glycosyl acetates are frequently used glycosyl donors in Lewis-acid catalyzed glycosylation reactions10 and other transformations.11Keywords
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