The Formation and Stereochemistry of [CoIII3(l-cys-N,S)n(aet)6−n]3−n Type S-Bridged Complexes (n=0–6, l-cys=l-cysteinate, and aet=2-aminoethanethiolate)
- 1 February 1989
- journal article
- research article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 62 (2) , 585-587
- https://doi.org/10.1246/bcsj.62.585
Abstract
Three kinds of S-bridged trinuclear complexes, ΔLLLΔLLL-[Co3(L-cys-N,S)6]3−, ΔLLLΔ- and ΔLLLΛ-[Co3(L-cys-N,S)3(aet)3]0, and [Co3(aet)6]3+, were formed by the reaction of a mixture of ΔLLL-fac-[Co(L-cys-N,S)3]3− (L-cys=L-cysteinate) and fac-[Co(aet)3] (aet=2-aminoethanethiolate) with [CoCl(NH3)5]2+. The reaction with an excess amount of Co2+ led to the formation of seven kinds of S-bridged complexes, [Co3(L-cys-N,S)n(aet)6−n]3−n](n=0–6).Keywords
This publication has 12 references indexed in Scilit:
- Preparation and Resolution of Bis[tris(2-aminoethaneselenolato)cobalt(III)-μ-Se, μ-Se′, μ-Se″]cobalt(III) ComplexBulletin of the Chemical Society of Japan, 1988
- S-Bridged Polynuclear Complexes. II. Formation and Some Properties of [M{Co(l-cys-N,S)3}2]-Type Complexes (M=Fe(III), Co(III), and Ni(II); l-cys=l-cysteinate)Bulletin of the Chemical Society of Japan, 1988
- S-Bridged Polynuclear Complexes. I. Selective Formation and Crystal Structure of (+)600CD-Bis[tris(l-cysteinato-N,S)cobaltate(III)-μ-S,μ-S′,μ-S″]cobalt(III) Nitrate PentahydrateBulletin of the Chemical Society of Japan, 1986
- Synthesis of [Co(CoL3)2]3+ by nitric acid oxidation of CoL3 (L = -SCH2CH2NH2) and induced electron transfer. Crystal structure of [Co(CoL3)2]2(SO4)Cl4Inorganic Chemistry, 1985
- Metal ion specificity in the oxidation of the coordinated mercapto groupInorganic Chemistry, 1978
- The reactivity of the coordinated mercapto group with various metal ionsInorganica Chimica Acta, 1977
- Structural characterization of crystalline tetrakis(2-aminoethanethiol)trinickel(II) chloride, [Ni{Ni(NH2CH2CH2S)2}2]Cl2. New basic trinuclear metal system containing nickel(II)-nickel(II) interactionsInorganic Chemistry, 1970
- Electronic and circular dichroism spectra of polynuclear 2-aminoethanethiol complexesInorganic Chemistry, 1967
- Complexes Derived from Strong Field Ligands. XIV. Heterometallic Trinuclear Complexes of β-MercaptoethylamineInorganic Chemistry, 1962
- Complexes Derived From Strong Field Ligands. XIII. The Complexes of β-Mercaptoethylamine with Nickel(II), Palladium(II), Cobalt(II), and Cadmium(II)Inorganic Chemistry, 1962