Air oxidation of a manganese(III) thioether chelate affords the first manganese(III) dihydrosalen complex with a pendant sulfoxide ligand
- 1 January 1995
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 5,p. 535-536
- https://doi.org/10.1039/c39950000535
Abstract
The aerobic oxidation of the manganese(III) dihydrosalen-thioether chelate rac-1 affords the novel manganese(III) sulfoxide complex rac-2; X-ray structural analysis of the latter reveals that only one of the two possible diastereomeric oxidation products is present in the crystal.Keywords
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