Enantioselective Aerobic Epoxidation of Acyclic Simple Olefins Catalyzed by the Optically Active β-Ketoiminato Manganese(III) Complex
- 1 July 1994
- journal article
- research article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 23 (7) , 1259-1262
- https://doi.org/10.1246/cl.1994.1259
Abstract
Enantioselective aerobic epoxidation of acyclic cis-olefins into the corresponding optically active epoxides was carried out with good-to-high enantioselectivities by using a new class of optically active β-ketoiminato manganese(III) complex catalyst, N,N′-ethylenebis(α-mesitoyl-β-ketoiminato)manganese(III) chloride. The key intermediate of the present epoxidation is also discussed.Keywords
This publication has 14 references indexed in Scilit:
- Optically active β-ketoiminato manganese(III) complexes as efficient catalysts in enantioselective aerobic epoxidation of unfunctionalized olefinsInorganica Chimica Acta, 1994
- A biomimetic catalyst for the asymmetric epoxidation of unfunctionalized olefins with hydrogen peroxideTetrahedron Letters, 1993
- Asymmetric epoxidation of olefins catalyzed by manganese complexes of chiral "strapped" porphyrins with diastereotopic faces. A novel strategy for stereochemical modeling of the active site of cytochrome P-450Journal of the American Chemical Society, 1992
- Catalytic and asymmetric epoxidation of olefins with iron complexes of twin-coronet porphyrins. A mechanistic insight into the chiral induction of styrene derivativesJournal of the American Chemical Society, 1991
- Asymmetric olefin epoxidation with sodium hypochlorite catalyzed by easily prepared chiral manganese(III) salen complexesThe Journal of Organic Chemistry, 1991
- Asymmetric hydroxylation, epoxidation, and sulfoxidation catalyzed by vaulted binaphthyl metalloporphyrinsThe Journal of Organic Chemistry, 1990
- Enantioselective epoxidation of unfunctionalized olefins catalyzed by salen manganese complexesJournal of the American Chemical Society, 1990
- Catalytic asymmetric epoxidation of unfunctionalized olefinsTetrahedron Letters, 1990
- Catalysis of alkene oxidation by nickel salen complexes using sodium hypochlorite under phase-transfer conditionsJournal of the American Chemical Society, 1988
- Catalytic asymmetric epoxidations with chiral iron porphyrinsJournal of the American Chemical Society, 1983