Proton Abstraction from Carbon Acids. Ab Initio Molecular Orbital Study on the Proton Abstraction from Acetaldehyde by NH2-, OH-, F-, SiH3-, PH2-, and SH-
- 1 January 1996
- journal article
- research article
- Published by American Chemical Society (ACS) in The Journal of Physical Chemistry
- Vol. 100 (9) , 3441-3447
- https://doi.org/10.1021/jp9517211
Abstract
No abstract availableThis publication has 39 references indexed in Scilit:
- Understanding the rates of certain enzyme-catalyzed reactions: Proton abstraction from carbon acids, acyl transfer reactions, and displacement reactions of phosphodiestersBiochemistry, 1993
- Understanding enzyme-catalyzed proton abstraction from carbon acids: details of stepwise mechanisms for .beta.-elimination reactionsJournal of the American Chemical Society, 1992
- Kinetics of deprotonation of arylnitromethanes by benzoate ions in acetonitrile solution. Effect of equilibrium and nonequilibrium transition state solvation on intrinsic rate constants of proton transfersJournal of the American Chemical Society, 1992
- Nonequilibrium transition-state solvation and Marcus work terms. Comparison of their contributions to solvent effects on intrinsic rate constants for proton transfersJournal of the American Chemical Society, 1989
- An ab initio molecular orbital study of the structures and energies of neutral and charged bimolecular complexes of NH3 with the hydrides AHn (A = N, O, F, P, S, and Cl)Journal of Computational Chemistry, 1989
- Hydrogen bonding and proton transfers involving triply bonded atoms. Acetylene and hydrocyanic acidJournal of the American Chemical Society, 1987
- Ab initio molecular orbital study of reactivity of active alkyl groups. I. Deprotonation of acetaldehyde with amide, hydroxide or fluoride ions.CHEMICAL & PHARMACEUTICAL BULLETIN, 1987
- Is hydrocyanic acid a normal acid? Proton transfer from hydrocyanic acid to bases and small inhibition of proton exchange by acidJournal of the American Chemical Society, 1985
- Theoretical analysis of proton transfers in symmetric and asymmetric systemsThe Journal of Physical Chemistry, 1985
- Proton Transfer, Acid‐Base Catalysis, and Enzymatic Hydrolysis. Part I: ELEMENTARY PROCESSESAngewandte Chemie International Edition in English, 1964