The Stereochemistry of Organometallic Compounds. XXX. Hydrocyanation of Alkynol Ethers: a New Stereospecific Route to α-Alkylidene γ-Lactones
- 1 January 1988
- journal article
- research article
- Published by CSIRO Publishing in Australian Journal of Chemistry
- Vol. 41 (2) , 251-261
- https://doi.org/10.1071/ch9880251
Abstract
The regioselectivity of hydrocyanation of a range of protected α- and β-hydroxyalkynes has been investigated and shown to be highly susceptible to steric effects. Some of the products from hydrocyanation of protected β-hydroxyalkynes have been converted into α-alkylidene γ- lactones.Keywords
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