Determination of Solvent‐Trapped Products Obtained by Photolysis of Aryl Azides in 2,2,2‐Trifluoroethanol
- 19 December 2007
- journal article
- research article
- Published by Wiley in Chemistry – An Asian Journal
- Vol. 3 (1) , 102-112
- https://doi.org/10.1002/asia.200700211
Abstract
A series of nonfluorinated and fluorinated aryl azides with varied functionality patterns were irradiated in 2,2,2‐trifluoroethanol with either a high‐pressure or a low‐pressure mercury lamp. Interestingly, one of the major products in these reactions was the result of the recombination of anilino and alkyl radicals to form the corresponding hemiaminal compounds. The structure of the recombination products was assigned unambiguously after proton/deuterium exchange experiments followed by MS and MS/MS analysis.Keywords
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