Mass spectra of inorganic molecules. Part II. Some polynuclear transition-metal carbonyls
- 1 January 1967
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 341-344
- https://doi.org/10.1039/j19670000341
Abstract
The mass spectra of the polynuclear carbonyls MnRe(CO)10, Fe2(CO)9, Os3(CO)12, Os4O4(CO)12, Co2(CO)8, Co4(CO)12, and Rh4(CO)12 are reported and where possible interpreted in terms of their structures. In all cases the molecular ion peak was observed and the predominant fragmentation scheme involved the successive removal of the CO groups before rupture of the central nucleus.Keywords
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