Cluster chemistry. VII. Some reactions of Ru3(CO)11(CNBut) with CO or Group 5B donor ligands: a route to mono- and di-substituted derivatives of Ru3(CO)12
- 1 January 1982
- journal article
- research article
- Published by CSIRO Publishing in Australian Journal of Chemistry
- Vol. 35 (5) , 935-939
- https://doi.org/10.1071/ch9820935
Abstract
The complex Ru3(CO)11(CNBut) is shown to react with CO or ligands (L) containing P, As or Sb as donor elements, by displacement of CO or CNBut, thus affording a new route to complexes Ru3(CO)11L [L = CO, PPh3, P(C6H4Me-p)3 or Pcy3] and Ru3(CO)10(CNBut)L [L = CNBut, PPh3, P(C6H4Me-p)3, PCy3, AsPh3 or SbPh3].Keywords
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