Stabilisation of metals in a low co-ordinative environment using the bis(trimethylsilyl)methyl ligand; coloured Sn II and Pb II alkyls, M[CH(SiMe3)2]2
- 1 January 1973
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 9,p. 317a
- https://doi.org/10.1039/c3973000317a
Abstract
(Me3Si)2CHLi and SnCl2 in ether at 0° give Sn[CH(SiMe3)2]2, which is diamagnetic at room temperature and behaves chemically as a singlet ‘stannylene’, yielding complexes such as R2SnM′(CO)5(M′= Cr or Mo).Keywords
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