Aminocyclitols. X. A Synthesis of Deoxyinosamine and Deoxyinosadiamine and Their Nuclear Magnetic Resonance Spectra
- 1 September 1966
- journal article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 39 (9) , 1931-1936
- https://doi.org/10.1246/bcsj.39.1931
Abstract
(±)-1-Deoxy-muco-inosamine-4, (±)-1-scyllo-inosamine-2 and (±)-2-deoxy-allo-inosadiamine-3, 5 pentaacetates have been synthesized from 1-deoxy-myo-inositol (I). The hydroxyl groups of I are mesylated, and the mesyloxy groups are replaced by azido groups. The reduction of the azido compounds, followed by acetylation, gives the pentaacetyl-deoxyinosamines and deoxyinosadiamine. Their structures have been established by means of a study of the proton magnetic resonance spectra.This publication has 13 references indexed in Scilit:
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