(η6-Arene)-tricarbonylchromium Complexes in Organic Synthesis: Stereoselective Carbon-Carbon Bond Formation via (η6-Arene)- tricarbonylchromium Carbocations
- 1 January 1986
- journal article
- research article
- Published by Georg Thieme Verlag KG in Synthesis
- Vol. 1986 (05) , 386-388
- https://doi.org/10.1055/s-1986-31645
Abstract
The benzylic acetate or hydroxy group of (η6-arene)-tricarbonylchromium complexes gave exo-substituted chromium complexes via Cr(CO)3-stabilized carbocations by the reaction with allyltrimethylsilane or propargyltrimethylsilane in the presence of Lewis acid.Keywords
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