Synthesis and crystal structure of a luminescent infinite 2D brick-wall network with two- and three-coordinate silver(I) atoms and ligand-unsupported silver–silver interactions
- 22 December 2000
- journal article
- letter
- Published by Royal Society of Chemistry (RSC) in New Journal of Chemistry
- Vol. 25 (2) , 210-212
- https://doi.org/10.1039/b008266j
Abstract
Assembly of a novel flexible tetradentate ligand 1,7-bis(4′-pyridyl)-2,6-diazaheptane (py-hep) with silver perchlorate hydrate provides an interesting two-dimensional (2D) brick-wall network: [Ag3(py-hep)2](ClO4)3·0.5CH3CN. The X-ray crystal structural analysis indicates that the framework consists of trigonal and linearly coordinated silver(I) atoms and ligand-unsupported metal–metal interactions. The complex shows photoluminescence in both the solid state and in acetonitrile solution.Keywords
This publication has 0 references indexed in Scilit: