Metal complexes of thio-hydroxamic acids. Part I. Crystal structure of bis(thioacetohydroxamato)nickel(II)
- 1 January 1968
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society B: Physical Organic
- p. 989-994
- https://doi.org/10.1039/j29680000989
Abstract
The crystal structure of bis(thioacetohydroxamato)nickel(II) has been determined by three-dimensional X-ray diffraction methods. There are four molecules in the unit cell, a= 15·59, b= 5·78, c= 9·53 Å, with space group P212121. The atomic co-ordinates were determined by Fourier and least-squares methods. The final R value over the 1181 independent reflections was 0·11. The nickel complex of thioacetohydroxamic acid forms five-membered chelate rings in which the metal is co-ordinated to sulphur and oxygen and the chelate rings are cis. Each ring is planar; the angle between the normals to the planes is 9·6°.Keywords
This publication has 0 references indexed in Scilit: