Unstable intermediates. Part LXXI. Electron spin resonance spectra of γ-irradiated trimethyl phosphate
- 1 January 1970
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 1334-1336
- https://doi.org/10.1039/j19700001334
Abstract
γ-Radiolysis of frozen trimethyl phosphate at 77°K, gave methyl and H2COP(O)(OMe)2 radicals. The methyl radical was lost at ca. 120°K, and the e.s.r. spectrum of the more stable radical at this temperature was characteristic of a system in which the α-hydrogen atoms were rapidly reorienting.Keywords
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