Asymmetric induction at silicon from prochiral silaethylenes
- 1 January 1980
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 9,p. 382-383
- https://doi.org/10.1039/c39800000382
Abstract
Prochiral silaethylene intermediates react with chiral alcohols to give unequal amounts of diastereomeric pairs of alkoxysilanes (up to 30% enantiomeric excess); this is the first example of asymmetric induction observed at a silicon centre involving a trigonal silicon species.Keywords
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