Synthesis and X-ray analysis of unusual planar tetra- and hexa-nuclear osmium clusters containing trifluoroacetate ligands
- 1 January 1988
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 20,p. 1358-1360
- https://doi.org/10.1039/c39880001358
Abstract
The compounds Os6(CO)18(O2CCF3)2(1) and Os4(CO)12(O2CCF3)2(2), isolated in low yields from the reaction of Os6(CO)18 with Hg(O2CCF3)2, have been found by X-ray analysis to have unusual planar arrangements of the metal atoms.Keywords
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