Novel octameric structure of the lithium primary amide [{ButN(H)Li}8] and its implication for the directed synthesis of heterometallic imide cages
- 1 January 1996
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 20,p. 2321-2322
- https://doi.org/10.1039/cc9960002321
Abstract
The crystalline lithium primary amide derived from tert-butylamine, [{ButN(H)Li}n], is structurally characterised by an X-ray diffraction study and shown to be a novel octameric (n= 8) ladder conformation, the cyclic, ‘double-crown’ nature of which implies molecules of this design could direct the synthesis of heterobimetallic (i.e. lithium and another metal) imide cage constructions.Keywords
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