Reactivity of Octahedral η1-Allenyl Iridium toward Hard Nucleophiles
- 1 March 1997
- journal article
- research article
- Published by American Chemical Society (ACS) in Organometallics
- Vol. 16 (6) , 1159-1166
- https://doi.org/10.1021/om960261a
Abstract
No abstract availableThis publication has 33 references indexed in Scilit:
- Synthesis of trans-(.sigma.-allenyl)platinum(II) and -palladium(II) compounds. X-ray crystal structure of trans-[PtBr{C(H):C:CMe2}(PPh3)2] and highly diastereoselective trans-cis isomerization of (.sigma.-allenyl)palladium(II) bromidesOrganometallics, 1994
- Nucleophilic substitution at the central allyl carbon atom of a (.pi.-allyl)platinum complexJournal of the American Chemical Society, 1994
- Interaction of (triphenylphosphine)2PtC2H4 with alkynyl(phenyl)iodonium triflates. Formation of .eta.3-propargyl/allenyl-Pt and .sigma.-acetylide-Pt complexes. Molecular structure of [(Ph3P)2Pt(.eta.3-CHCH3CCBu-tert)]OSO2CF3Organometallics, 1993
- Interconversion of .eta.1-propargyl, .eta.1-allenyl, and .eta.3-propargyl/allenyl ligands on platinum. Synthesis, structure, and reactivity of [(Ph3P)2Pt(.eta.3-CH2CCPh)]O3SCF3Organometallics, 1993
- A versatile route to the .beta.-substituted .pi.-allyl complexes via addition to a cationic .eta.3-propargyl complex of platinumJournal of the American Chemical Society, 1993
- Nucleophilic attack at the central carbon of a cationic (.eta.3-propargyl)rhenium complexJournal of the American Chemical Society, 1992
- Oxygen- and carbon-bound ruthenium enolates: migratory insertion, reductive elimination, .beta.-hydrogen elimination, and cyclometalation reactionsOrganometallics, 1991
- Photochemical reactions of diiron .mu.-alkenylidene complexes with hydrogen, trialkylsilanes, and diazo compounds: cleavage to alkenes, vinylsilanes and allenesJournal of the American Chemical Society, 1988
- Coordinated trifluoromethanesulfonate and fluorosulfateChemical Reviews, 1986
- Reaction of 3-chloro-2-(trimethylsiloxy)prop-1-ene with low-valent metal complexes. Syntheses of metallacyclobutan-3-ones of osmium, iridium, and platinum and the X-ray structure of chloro(carbonyl)bis(triphenylphosphine)iridacyclobutan-3-oneJournal of the Chemical Society, Chemical Communications, 1986