A Stereoselective Synthesis of Antimycinone A3 and Its Stereoisotners
Open Access
- 1 January 1973
- journal article
- Published by Oxford University Press (OUP) in Agricultural and Biological Chemistry
- Vol. 37 (4) , 915-920
- https://doi.org/10.1271/bbb1961.37.915
Abstract
Antimycinone A3, which is a neutral fragment of mild alkaline hydrolysate of antimycin A3, and its stereoisomers were synthesized stereoselectively from methyl trans-2-n-butylpent-3-enoate or methyl cis-2-n-butylpent-3-enoate, and natural antimycinone A3 was proved to possess Hα-Hβ and Hβ-Hγ trans configuration.Keywords
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