Absorption spectrum of the carbon tetrachloride molecular cation in noble-gas matrices
- 1 January 1983
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics
- Vol. 79 (9) , 1417-1424
- https://doi.org/10.1039/f29837901417
Abstract
Carbon tetrachloride diluted in argon, krypton or xenon and subjected to vacuum-ultraviolet radiation during and after condensation gave strong photosensitive absorptions at 425, 430 and 455 nm, respectively, which are assigned to CCl4 +. This study suggests that absorptions in this region following radiolysis of CCl4 in hydrocarbon glasses are probably due to CCl4 + as well and that structural relaxation follows ionization of CCl4 in the solid phase.Keywords
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