Caveats for poly(methimazolyl)borate chemistry: the novel inorganic heterocycles [H2C(mt)2BR2]Cl (mt = methimazolyl; BR2= BH2, BH(mt), 9–BBN)

Abstract
Whilst frequently used for reactions of poly(methimazolyl)borates, dichloromethane is not an innocent solvent, but rather slowly forms heterocyclic salts [H2C(mt)2BR2]Cl, three examples of which (BR2 = BH2, BH(mt), 9-borabicyclononyl) have been structurally characterised to confirm the unprecedented B(NCS)2C connectivity.

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