Diurnal Variation of Aerosol Trace Element Concentrations In Livermore, California*

Abstract
Concentrations of 15 atmospheric aerosol trace elements in Livermore, California, were measured by neutron activation analysis in 2–hour filter samples for 58 hours during 3 typical summer days. All elements showed cyclic patterns with concentration variations of factors of 3 to 10. Three basic patterns were seen: (1) Na and Cl in phase with each other and nearly perfectly out of phase with the others, with a late night maximum for both; (2) All other elements except Br, showing a midafternoon maximum; and (3) Br, which had morning and evening peaks suggestive of automotive sources. Details of the patterns suggest a diurnal circulation model for the Livermore Valley involving alternation between fresh and aged marine air. Comparison of the trace element patterns with those of CO, NO2, and “oxidant” was not definitive.

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