Photoelectron spectra of some decahydrotrimethanoanthracenes: observation of large π orbital interactions through six bonds and an apparent violation of the trans rule
- 1 January 1983
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 10,p. 573-575
- https://doi.org/10.1039/c39830000573
Abstract
Photoelectron spectroscopic studies of the trimethanoanthracenes have revealed a large π orbital interaction through six bonds, an apparent violation of the trans rule and a new and effective way by which a CH2 group can act as a through-bond relay.Keywords
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