Highly Stereoselective Synthesis of (±)-Aminobromocyclitol Derivatives from Furan
- 1 January 1991
- journal article
- letter
- Published by Georg Thieme Verlag KG in Synlett
- Vol. 1991 (07) , 469-471
- https://doi.org/10.1055/s-1991-20763
Abstract
The Diels-Alder adduct (2-cyano-7-oxabicyclo[2.2.1]-hept-5-en-2-yl acetate) of furan and 1-cyanovinyl acetate was converted to N-[(1RS,2RS,3RS,4SR, 6RS)-2,3,4-triacetoxy-6-bromocyclohex-1-yl]benzamide and to N-[(1RS, 2RS,3SR,4RS,5SR,6SR)-2,3,4,5-tetraacetoxy-6-bromocyclohex-1-yl]benzamide with high stereoselectivity.Keywords
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