High-resolution angle-resolved photoelectron spectrum of the B2Σu+state in CO2+
- 28 April 1984
- journal article
- Published by IOP Publishing in Journal of Physics B: Atomic and Molecular Physics
- Vol. 17 (8) , L259-L264
- https://doi.org/10.1088/0022-3700/17/8/005
Abstract
The photoelectron spectrum of CO2 excited by polarised He I radiation is investigated in the binding energy region 18.0-18.7 eV, using a focusing VUV polariser at an energy resolution of 15 meV (FWHM). Comparison of spectra taken at different polariser settings makes it possible to give vibrational assignments and beta values for 18 bands belonging to the B2 Sigma u+ state and 6 bands from the A2 Pi u state. The v3 energy in the B state is 230 meV.Keywords
This publication has 14 references indexed in Scilit:
- A Theoretical Investigation of the Low Lying Electronic States of CO2+in Both Linear and Bent ConfigurationsPhysica Scripta, 1984
- The He i photoelectron spectra of CO2, CS2, and OCS: Vibronic couplingThe Journal of Chemical Physics, 1983
- Photoelectron asymmetry parameters of Ar, Kr, Xe, H2, N2, O2, CO and CO2: New measurements and a reconsideration of literature dataJournal of Electron Spectroscopy and Related Phenomena, 1980
- Photoelectron angular distribution of simple molecules at 30.4 nm photonsJournal of Electron Spectroscopy and Related Phenomena, 1979
- Angular-distribution He(I)/Ne(l) photoelectron Spectra of H2, N2 and other small moleculesJournal of Electron Spectroscopy and Related Phenomena, 1979
- Angular distribution of photoelectrons at 584 Å using polarized radiationJournal of Electron Spectroscopy and Related Phenomena, 1976
- The Emission Spectrum of the CO2+ Ion: Band SystemCanadian Journal of Physics, 1975
- Angular distribution of the photoelectron spectrum of CO2, COS, CS2, N2O, H2O, and H2SJournal of Electron Spectroscopy and Related Phenomena, 1973
- Studies on the photoionisation of the linear triatomic molecules: N2O, COS, CS2 and CO2 using high-resolution photoelectron spectroscopyInternational Journal of Mass Spectrometry and Ion Physics, 1969
- Photoelectron spectra and ionic structure of carbon dioxide, carbon disulphide and sulphur dioxideInternational Journal of Mass Spectrometry and Ion Physics, 1968