Preparation, Characterization, and Some Reactions of Cationic Hydrido Carboxylato Complexes of Molybdenum(IV), [MoH2(O2CR)(dppe)2]+
- 1 November 1986
- journal article
- research article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 59 (11) , 3489-3494
- https://doi.org/10.1246/bcsj.59.3489
Abstract
Cationic carboxylatodihydridomolybdenum(IV) complexes, [MoH2(O2CR)(dppe)2]BPh4 (R=CH3, C2H5, CH2=CH, and CH2=C(CH3); dppe=Ph2PCH2CH2PPh2), were prepared by treating [MoH4(dppe)2] with RCOOH followed by anion exchange with NaBPh4, and characterized spectroscopically. A possible pathway of the reaction is discussed on the basis of the experiment using CH3COOD. Light irradiation of the EtOH solution of the cationic acetato complex in the presence and absence of CO afforded the known cis-[Mo(CO)2(dppe)2] and the neutral hydridoacetato complex, [MoH(O2CCH3)(dppe)2], respectively.Keywords
This publication has 11 references indexed in Scilit:
- Selective activation of olefinic carbon-hydrogen bonds. Reaction of a hydridomolybdenum complex with methacrylic esters to form hydrido-alkenyl complexesOrganometallics, 1986
- The reaction of tetra(μ-trifluoroacetato)dimolybdenum with trimethylchlorosilane and propionitrile: products with novel stereochemistriesInorganica Chimica Acta, 1984
- Bidodecahedral coordination geometry in a dimolybdenum tetrahydride containing three fluoride bridges: crystal and molecular structure of .mu.-trifluoro-bis[tris(methyldiphenylphosphine)dihydromolybdenum] tetrafluoroborate ([((PMePh2)3H2Mo)2(.mu.-F)3]BF4)Journal of the American Chemical Society, 1983
- Oxidation and acidolysis of MoH4(PR3)4Inorganic Chemistry, 1982
- Stereochemistry of bis(carboxylato)dichlorobis(tertiary phosphine)dimolybdenum complexes. Crystal and molecular structure of two isomers of Mo2(O2CCMe3)2Cl2(PEt3)2Inorganic Chemistry, 1982
- Quadruply bonded dimolybdenum compounds of the type Mo2(O2CR)2X2(PR3)2: evidence for kinetic and structural trans effectsJournal of the American Chemical Society, 1982
- Isomeric organomolybdenum carboxylate derivativesJournal of Organometallic Chemistry, 1981
- Chemical and x-ray structural studies on the (acetato)- and (trifluoroacetato)pentacarbonylmetalates of chromium and molybdenumJournal of the American Chemical Society, 1981
- Preparation and characterization of some dimolybdenum(II) carboxylatesInorganic Chemistry, 1976
- MOLYBDENUM(II) TRIFLUORO ACETATE DIMERJournal of Coordination Chemistry, 1972