Comment on the critical behavior in the Percus-Yevick equation
- 1 October 1985
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review A
- Vol. 32 (4) , 2526-2529
- https://doi.org/10.1103/physreva.32.2526
Abstract
The internal consistency of the procedure described by Brey, Santos, and Rull [Phys. Rev. A 26, 2993 (1982)] to determine the thermodynamical properties of the Lennard-Jones classical fluid in the critical region on the basis of the Percus-Yevick (PY) equation is discussed and found inadequate. New results for the solution of this equation near the critical point for a much larger range in r space are presented. We consider the sum of two Yukawa potentials as the pair interaction. Our results are in complete agreement with the critical behavior found with models exactly soluble (adhesive hard spheres and lattice gas) in the PY approximation: classical critical exponents but a nonclassical scaling function that leads to an asymmetry between liquid and vapor with a true spinode present only for ρ>.
Keywords
This publication has 11 references indexed in Scilit:
- Critical behaviour of the lattice gas model in the Percus-Yevick approximationPhysica A: Statistical Mechanics and its Applications, 1984
- Critical phenomena of the Lennard-Jones fluid on the basis of perturbation theoriesJournal of Physics C: Solid State Physics, 1983
- Critical behavior of the Yukawa fluid in the mean spherical approximationThe Journal of Chemical Physics, 1983
- The critical region in the Percus–Yevick approximation. A numerical study for a Lennard-Jones potentialThe Journal of Chemical Physics, 1982
- Critical behavior in the Percus-Yevick equation for a Lennard-Jones potentialPhysical Review A, 1982
- Critical point scaling in the Percus-Yevick equationPhysica A: Statistical Mechanics and its Applications, 1981
- Absence of power-law behavior of the hypernetted chain equationPhysical Review A, 1981
- Critical Point in the Percus-Yevick TheoryPhysical Review A, 1972
- Percus–Yevick Equation for Hard Spheres with Surface AdhesionThe Journal of Chemical Physics, 1968
- Integral equation for classical fluids and the lattice gasPhysics Letters, 1964