Ternary Molybdenum Sulfides of the Heavy Alkali Metals
Open Access
- 1 July 1980
- journal article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung B
- Vol. 35 (7) , 929-930
- https://doi.org/10.1515/znb-1980-0727
Abstract
Two series of ternary molybdenum sulfides, AxMO4S6 (A = K, Rb, Cs) and A2MO15S20 (A = K, Rb), were prepared by reduction of molybdenum disulfide with alkali metals in alkali halide melts at 1100-1300 K. All compounds are hexagonal and show electronic conductivity; structural characteristics suggest isolated [Mo/S]x- ∞chains as lattice elements for AxMo4S6Keywords
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