Comparison of the Structures of Stretched Linear Polymers
- 1 January 1945
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 13 (1) , 37-42
- https://doi.org/10.1063/1.1723965
Abstract
Published x‐ray data from crystalline selenium and tellurium and from stretched sulfur (amorphous), polyethylene, polyisobutylene, polyvinyl alcohol, polyvinyl chloride, polyvinylidine chloride, polyoxymethylene, polyoxyethylene, polyethylene disulfide, polyethylene tetrasulfide, and polyphosphonitrile chloride are compared. In most cases the experimental identity distance in the direction of the chain axes and the expected interatomic distances and interbond angles are found to be in agreement with the assumption that the chain atoms form a regular spiral, unidirectional in each chain and of uniform pitch. Apparent exceptions are briefly discussed.Keywords
This publication has 13 references indexed in Scilit:
- The Structure of the Trimer of Phosphonitrile Chloride, P3N3Cl6Journal of the American Chemical Society, 1943
- An X-Ray Study of the Structure of Polyvinyl Alcohol*Journal of the American Chemical Society, 1941
- X-Ray Examination of Polyisobutylene1Journal of the American Chemical Society, 1940
- The crystal structure of long-chain normal paraffin hydrocarbons. The “shape” of the <CH2 groupTransactions of the Faraday Society, 1939
- X-ray spectrography of polymers and in particular those having a rubber-like extensibilityTransactions of the Faraday Society, 1936
- Sur le chlorure de poly‐phosphornitrile, caoutchouc inorganiqueHelvetica Chimica Acta, 1936
- Faserdiagramme von PolyvinylalkoholThe Science of Nature, 1935
- Sur le soufre filiforme et sa structureHelvetica Chimica Acta, 1934
- Röntgenuntersuchungen über die Struktur der Polymerisationsprodukte des FormaldehydsAnnalen der Physik, 1927
- L. The crystal structures of the rhombohedral forms of selenium and telluriumJournal of Computers in Education, 1924