A novel type of tetranuclear copper(II) cluster, containing deprotonated 3-(pyridin-2-yl)-5-(pyrazin-2-yl)-1,2,4-triazole (Hppt) as a diatomic bridging ligand. Preparation, magnetism, and X-ray crystal structure of [Cu(µ-ppt)(H₂O)]₄(NO₃)₄(H₂O)₁₂

1 January 1986

journal article
research article
Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications

No. 18,p. 1430-1431
https://doi.org/10.1039/c39860001430

Abstract

The title compound, characterized by means of an X-ray structure analysis, represents the first example of a tetranuclear co-ordination compound with only diatomic bridges.

Keywords

COPPER

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A novel type of tetranuclear copper(II) cluster, containing deprotonated 3-(pyridin-2-yl)-5-(pyrazin-2-yl)-1,2,4-triazole (Hppt) as a diatomic bridging ligand. Preparation, magnetism, and X-ray crystal structure of [Cu(µ-ppt)(H2O)]4(NO3)4(H2O)12

Abstract

Keywords

A novel type of tetranuclear copper(II) cluster, containing deprotonated 3-(pyridin-2-yl)-5-(pyrazin-2-yl)-1,2,4-triazole (Hppt) as a diatomic bridging ligand. Preparation, magnetism, and X-ray crystal structure of [Cu(µ-ppt)(H₂O)]₄(NO₃)₄(H₂O)₁₂